نانومقیاس

نانومقیاس

مطالعه ی آزمایشگاهی تاثیر امولسیون پیکرینگ GO-SiO2-TiO2-SDS بر روی کشش بین سطحی

نوع مقاله : مقاله پژوهشی

نویسندگان
1 - گروه مهندسی نفت، دانشکده نفت و مهندسی شیمی، واحد علوم و تحقیقات، دانشگاه آزاد اسلامی، تهران، ایران
2 گروه مهندسی نفت، دانشکده نفت اهواز، دانشگاه صنعت نفت، اهواز، ایران
3 گروه زمین شناسی، دانشکده علوم و فناوری های همگرا، واحد علوم و تحقیقات، دانشگاه آزاد اسلامی، تهران، ایران
4 گروه مهندسی نفت، دانشکده نفت آبادان، دانشگاه صنعت نفت، آبادان، ایران
چکیده
کشش بین سطحی (IFT)، یکی از جدی ترین موانع، بر سر راه خروج و تولید نفت، از حفرات مخزن می باشد که سبب نگه داشت مقادیر بسیار زیاد نفت، به صورت باقیمانده (به دام افتاده)، در حفرات مخزن و در نتیجه، کاهش چشمگیر راندمان جابه جایی میکروسکوپیک و در پی آن، کاهش چشمگیر ضریب بازیافت نفت، از مخزن می شود. یکی از جدیدترین روش ها، به منظور کاهش کشش بین سطحی و تولید نفت باقیمانده از حفرات مخزن، استفاده از امولسیون های پیکرینگ می باشد. بر همین اساس، این تحقیق قصد دارد که برای اولین بار، امولسیون پیکرینگی، از ترکیب نانوکامپوزیت نوین GO-SiO2-TiO2، در موثرترین غلظت نانوکامپوزیت و سورفکتانت SDS، در غلظت بحرانی میسل (CMC)، ساخته شود که از طریق کاهش قابل ملاحظه ی کشش بین سطحی، بتواند سبب افزایش چشمگیر ضریب بازیافت نفت از مخزن، گردد. برای این منظور، نانوکامپوزیت GO-SiO2-TiO2، سنتز شد. علاوه بر این، با استفاده از آنالیزهای: FESEM، EDXS، Map، FTIR، XRD و TGA، سنتز نانوکامپوزیت مذکور تایید شد و خصوصیات آن نیز بررسی گردید. سپس، غلظت 500 پی پی ام سورفکتانت SDS، با IFT 2.48 میلی نیوتن بر متر و نیز غلظت 2500 پی پی ام نانوکامپوزیت GO-SiO2-TiO2، با IFT 1.11 میلی نیوتن بر متر، به ترتیب، CMC سورفکتانت و موثرترین غلظت نانوکامپوزیت، تعیین شدند. سپس، بر اساس غلظت های مذکور، امولسیون پیکرینگ GO-SiO2-TiO2–SDS، ساخته شد و مقدار IFT بین این امولسیون و نفت سفید، 0.21 میلی نیوتن بر متر اندازه گیری شد. این یافته، نشان دهنده ی کاهش قابل ملاحظه ی IFT، به دلیل استفاده از امولسیون پیکرینگ GO-SiO2-TiO2–SDS، می باشد. بنابراین، استفاده از امولسیون پیکرینگ مذکور، با کاهش قابل توجه IFT، می تواند سبب افزایش چشمگیر تولید نفت باقیمانده از حفرات مخزن و در نتیجه، افزایش ضریب بازیافت نفت، از مخزن شود.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Experimental Study of the Effect of GO-SiO2-TiO2-SDS Pickering Emulsion on Interfacial Tension

نویسندگان English

Arash Pourabdol Shahrekordi 1
Ghasem Zargar 2
Seyed Jamal Sheikh Zakariaei 3
Abbas Khaksar Manshad 4
1 Department of Petroleum Engineering, Faculty of Petroleum and Chemical Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran
2 Department of Petroleum Engineering, Ahvaz Faculty of Petroleum Engineering, Petroleum University of Technology, Ahvaz, Iran
3 Department of Earth Sciences, Faculty of Converging Sciences and Technologies, Science and Research Branch, Islamic Azad University, Tehran, Iran
4 Department of Petroleum Engineering, Abadan Faculty of Petroleum Engineering, Petroleum University of Technology, Abadan, Iran
چکیده English

Interfacial tension (IFT) is one of the most serious obstacles on the way to the exit and production of oil from the reservoir pores, causing a large amount of oil to be kept as residual (trapped) in these pores. It also leads to a significant reduction in the microscopic displacement efficiency and, subsequently, a considerable decline in the oil recovery factor from the reservoir. One of the most recent methods is to use Pickering emulsions to reduce the IFT and produce residual oil from the reservoir pores. Accordingly, this research aimed to prepare a Pickering emulsion by combining the novel GO-SiO2-TiO2 nanocomposite at its most effective concentration with the SDS surfactant at a critical micelle concentration (CMC) for the first time, which can significantly increase the oil recovery factor from the reservoir through a significant decrease in IFT. The GO-SiO2-TiO2 nanocomposite was synthesized for this purpose. In addition, the synthesis of the mentioned nanocomposite was confirmed using FESEM, EDXS, Map, FTIR, XRD, and TGA analyses, and its properties underwent investigation. The 500-ppm concentration of the SDS surfactant and the 2500-ppm concentration of the GO-SiO2-TiO2 nanocomposite (with IFT values of 2.48 mN/m and 1.11 mN/m, respectively) were then selected as the CMC of the surfactant and the most effective concentration of the nanocomposite, respectively. Next, the GO-SiO2-TiO2-SDS Pickering emulsion was prepared based on the mentioned concentrations, and the IFT value between this emulsion and kerosene was measured at 0.21 mN/m. This finding indicated a significant reduction in the IFT due to using the GO-SiO2-TiO2–SDS Pickering emulsion. Therefore, using the mentioned Pickering emulsion can significantly increase the production of residual oil from the reservoir pores and enhance the oil recovery factor from the reservoir by reducing the IFT substantially.

کلیدواژه‌ها English

SDS surfactant solutions
GO-SiO2-TiO2 nanofluids
Pickering emulsions
Du Noü
y ring
IFT reduction
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دوره 12، شماره 2
تابستان 1404
صفحه 168-187

  • تاریخ دریافت 15 مرداد 1403
  • تاریخ بازنگری 15 مهر 1403
  • تاریخ پذیرش 24 آذر 1403