نانومقیاس

نانومقیاس

بررسی خواص نورگرمایی کامپوزیت آئروژل گرافن/ نانو گل‌های Cu2S و کاربرد آن در شیرین‌سازی آب

نوع مقاله : مقاله پژوهشی

نویسندگان
1 گروه فیزیک، دانشکده علوم، دانشگاه شهید چمران اهواز، اهواز، ایران
2 گروه فیزیک،دانشکده علوم، دانشگاه شهید چمران اهواز، اهواز، ایران
چکیده
چکیده:استفاده از اثر نورگرمایی راهی مناسب برای تولید بخار آب خورشیدی بدون استفاده از سوخت‌های فسیلی است. در این پژوهش کامپوزیت آئروژل گرافن /نانو گل‌های Cu2S تهیه و از آنها به منظور تبخیر سریع آب استفاده شد. نانو گل‌های Cu2S به روش حلالی- حرارتی تهیه و با استفاده از آنالیز‌های XRD و SEM مشخصه‌یابی شدند و سپس مشخصات نوری این مواد با استفاده از آنالیزهای UV-Vis ، PL و FTIR بررسی شدند. همچنین آئروژل گرافن با استفاده از خشک کردن در فشار محیط تهیه شد. کامپوزیت این دو ماده به روش ریخته گری قطره‌ای تهیه شد. برای بررسی اثر نورگرمایی، این مواد تحت تابش نور مرئی با شدت W/m2 2000 به مدت یک ساعت قرار گرفتند. تغییرات دمای غلظت‌های مختلف 10، 20 و g/l 30 از این مواد به طور جداگانه نسبت به آب خالص در حضور و عدم حضور نور مقایسه شدند و مشخص شد با افزایش غلظت نانو گل‌ها در آب، دما افزایش قابل توجه‌ای داشته تا جایی که در غلظت g/l 30، دما از 25 درجۀ سانتی‌گراد به 4/48 درجه رسید. همچنین میزان کاهش جرم آب در حضور این نانو مواد با غلظت g/l ۳۰ به مقدار kg/m2 64/3 رسید. سپس از کامپوزیت آئروژل گرافن/نانو گل‌های Cu2S به منظور بررسی همزمان اثر هر دو ماده در آب در غلظت‌های مختلف استفاده شد و مشاهده شد پس از گذشت 60 دقیقه، کامپوزیت با غلظت g/l 30 باعث تغییر دمای آب تا حدود 32 درجۀ سانتی گراد شده است که 6/8 درجه بیشتر از Cu2S تنها و 4 درجه بیشتر از آئروژل تنها می‌باشد. میزان کاهش جرم آب با حضور این کامپوزیت و تحت تابش نور مرئی با شدت W/m2 2000 به مقدار kg/m2 96/3 رسید.
کلیدواژه‌ها

موضوعات


عنوان مقاله English

Investigation of the photothermal properties of the graphene aerogel/Cu2S nanoflower composite and its application in water evaporation

نویسندگان English

Mansoor Farbod 1
Alireza Mobarakmoab 2
1 Department of physics, shahid chamran university of Ahvaz
2 Department of Physics, Faculty of Sciences, Shahid Chamran University of Ahvaz, Ahvaz, Iran
چکیده English

Abstract:The use of photothermal effect is an appropriate method for generating solar steam without the use of fossil fuels. In this study, a graphene aerogel/Cu2S nanoflower composite was prepared and used for rapid water evaporation. The Cu2S nanoflowers were synthesized using a solvothermal method and characterized using XRD and SEM analyses. The optical properties of these materials were investigated using UV-vis, PL, and FTIR analyses. Additionally, the graphene aerogel was prepared by drying under ambient pressure. The composite of these two materials was prepared using a droplet casting method. To study the photothermal effect, these materials were exposed to visible light irradiation with an intensity of 2000 W/m2 for one hour. The temperature changes of different concentrations (10, 20, and 30 g/l) of these materials were compared to pure water, both in the presence and absence of light, and it was found that the presence of these materials in water leads to an increase in temperature changes and the rate of water evaporation. with an increase in the concentration of nano-flowers in water, the temperature showed a significant increase, reaching 48.4 degrees Celsius at a concentration of 30 g/l, compared to 25 degrees Celsius initially. moreover, the amount of water mass reduction, indicating water evaporation, reached 3.64 kg/m2 at the highest concentration. Furthermore, the graphene aerogel/Cu2S nanoflower composite was used to simultaneously investigate the effects of both materials in water at different concentrations, and the results showed after 60 minutes, the composite with a concentration of 30 g/l caused a temperature change of approximately 32 degrees Celsius, which is 8.6 degrees higher than Cu2S alone and 4 degrees higher than graphene aerogel alone. The reduction in water mass in the presence of this composite under visible light irradiation at an intensity of 2000 W/m2 reached 3.96 kg/m2.

کلیدواژه‌ها English

photothermal
graphene aerogel/Cu2S nanoflower composite
water evaporation
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دوره 11، شماره 1
بهار 1403
صفحه 28-17

  • تاریخ دریافت 06 آبان 1402
  • تاریخ بازنگری 02 دی 1402
  • تاریخ پذیرش 11 اسفند 1402