نانومقیاس

نانومقیاس

اکسایش گزینشی الکل‌های بنزیلیک به آلدهید با استفاده از چارچوب‌ فلز-آلی نانومتخلخل پورفیرین دار در شرایط سبز

نوع مقاله : مقاله پژوهشی

نویسندگان
محدثه اکبریان
اسماعیل سنچولی
علیرضا اویسی
صبا دلیران
گروه شیمی، دانشگاه زابل، زابل، ایران
چکیده
در سال های اخیر، ساختارهای متخلخل چارچوب‌های فلز-آلی (MOF)، بنابه ویژگی‌های منحصر به ‌فرد خود مانند مساحت سطح ویژه بالا، تخلخل بسیار بالا، پایداری شیمیایی-گرمایی بالا، قابلیت پیش بینی و تنظیم ساختار و خواص قبل از سنتز، توجه محققین زیادی را در بخش‌های مختلف صنعتی و دانشگاهی به خود جلب کرده است. در پژوهش حاضر یک چارچوب فلز-آلی بر پایه‌ی پورفیرین آهن و گره‌های اکسیژن-آهن (PCN-600(Fe))، تحت شرایط سنتزی سولوترمال ساخته شد و فعالیت کاتالیزوری آن به عنوان یک کاتالیست ناهمگن برای اکسیداسیون اکسایشی بنزیل الکل‌ها به بنزآلدهیدها مورد بررسی قرار گرفت. کاتالیست مورد نظر با استفاده از روش‌های مختلفی مانند طیف‌بینی زیر قرمز با تبدیل فوریه (FT-IR)، دستگاه الگوی پراش اشعه ایکس (PXRD)، میکروسکوپ الکترونی روبشی (SEM) و پراکندگی انرژی اشعه ایکس (EDX) شناسایی شد. برای اولین بار با استفاده از این کاتالیست، بنزیل الکل ها بدون هیچ ماده افزودنی و تحت شرایط بدون حلال به آلدهیدهای مربوطه بصورت گزینشی با بازده عالی اکسید می شوند. محصولات توسط کروماتوگرافی لایه نازک (TLC) و دستگاه کروماتوگرافی گازی-جرمی (GC-MS) شناسایی شدند. نتایج نشان می دهند که MOF مورد استفاده دارای فعالیت کاتالیستی خوبی نسبت به دیگر کاتالیست های گزارش شده می باشد و تا چندین بار قابلیت بازیابی در واکنش را دارد.
کلیدواژه‌ها
مواد نانومتخلخل
چارچوب فلز-آلی
PCN-600(Fe)
سولوترمال
کاتالیزور
اکسایش

موضوعات

عنوان مقاله English

Selective oxidation of benzylic alcohols to aldehyde using porphyrin-containing nanoporous metal-organic framework under green conditions

نویسندگان English

Mohadeseh Akbarian
esmael sanchooli
Ali reza Oveisi
Saba Daliran
University of Zabol
چکیده English

In recent years, porous metal-organic frameworks (MOFs) have attracted much attention by researchers in various industrial and academic active areas due to their unique characteristics such as high specific surface area, high porosity, high chemical and thermal stability, predictable structures and tunable properties. In the present study, an iron-based porphyrinic MOF (PCN-600(Fe); PCN is porous coordination network) was prepared and used for the first time as an efficient heterogeneous catalyst for the selective oxidation of benzyl alcohols to benzaldehydes under solvent-free conditions. The nominal catalyst was characterized by using different techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction pattern (PXRD), scanning electron microscopy (SEM), and X-ray energy dispersive (EDX). The products were identified by thin layer chromatography (TLC) and gas chromatography-mass chromatography (GC-MS). The results showed that the PCN-600(Fe) has good catalytic activity compared to other reported catalysts. The nominal solid can be recovered and reused several times without any significant change in the activity.

کلیدواژه‌ها English

Nanoporous materials
metal-organic framework
PCN-600(Fe)
solvothermal
catalyst
oxidation

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نانومقیاس
دوره 11، شماره 2
تابستان 1403
صفحه 43-32

  • تاریخ دریافت 23 بهمن 1402
  • تاریخ بازنگری 17 اردیبهشت 1403
  • تاریخ پذیرش 14 خرداد 1403