نانومقیاس

نانومقیاس

حذف یون‌های مس II و سرب II توسط بنتونیت اصلاح شده با Nd-TiO2 و برخی پلیمرهای آلی

نویسندگان
1 دانشکده علوم پایه، واحد یادگار امام خمینی (ره) شهرری، دانشگاه آزاد اسلامی، تهران
2 دانشکده علوم پایه، واحد یادگار امام خمینی )ره( شهرری، دانشگاه آزاد اسلامی، تهران
3 باشگاه پژوهشگران جوان و نخبگان، واحد یادگار امام خمینی (ره)شهرری، دانشگاه آزاد اسلامی، تهران
چکیده
به‌منظور افزایش ظرفیت جذب، با استفاده از دو پلیمر پلی‌اتیلن‌گلیکولPEG و پلی‌وینیل‌پیرولیدون PVP، نانو کامپوزیت‌های Nd-TiO2/PEG/Bentonite و Nd-TiO2/PVP/bentonite به روش سل-ژل ساخته شد. میکرو ساختار نانو کامپوزیت‌های سنتزی توسط آنالیزهای XRD، FESEM و EDS مورد بررسی قرار گرفت و ساختار مورد انتظار و تشکیل فاز آناتاز تیتانیا را تائید کرد. از نانو جاذب‌های ساخته‌شده برای حذف دو یون مس II و سرب II از آب استفاده و پارامترهای مؤثر بر حذف، بهینه‌سازی شدند که عبارت‌اند از: زمان تماس برای نانو کامپوزیت TiO2/PEG/bentonite و TiO2/PVP/bentonite به ترتیب برابر 30 و 60 ثانیه و مقدار جاذب، pH و دما برای هر دو نانو جاذب به ترتیب برابر 005/0 گرم، 7 و ℃ 25 است. بررسی اثر یون‌های مزاحم هیچ تأثیر قابل‌ملاحظه‌ای روی راندمان حذف نداشت. مطالعه ایزوترم جذب نشان داد که تمام داده‌های تجربی از مدل ایزوترم جذب لانگمویر پیروی می‌کنند.
کلیدواژه‌ها

عنوان مقاله English

Removal Cu(II) and Pb(II) Ions by Modified Bentonite with NdTiO2 and Some Organic Polymers

نویسندگان English

S. Samadi 1
A. Parsa 2
A. Hadian 2
A. Partoyi Motlagh 2
S.A. Zakaria 3
چکیده English

In order to increase adsorption capacity, Nd-TiO2/PEG/Bentonite and Nd-TiO2/PVP/Bentonite nanocomposites were synthesized by PEG and PVP, with sol-gel method. Microstructure nanocomposites were investigated by XRD, FESEM and EDS analyses. These analyzes confirmed the expected structure and formation of anatase titania phase. Synthetic nano-sorbents used to removal of Cu II and Pb II ions from water. The affective removal parameter was optimized and that contact time for TiO2/PEG/bentonite and TiO2/PVP/bentonite nanocomposites is 30 and 60 seconds, respectively, and for both nanocomposite, sorbent amount, temperature and pH were 0.005 g, 7 and 25℃, respectively. Investigation of interfering ions didn’t have any considerable impact on removal efficiency. The isotherm adsorption shows all the experimental data followed the Langmuir model.

کلیدواژه‌ها English

removal
copper (II)
lead (II)
bentonite
titania
[1] R. Ahmad, A. Mirza, “Sequestration of heavy metal ions by Methionine modified bentonite/Alginate (Meth-bent/Alg): A bionanocomposite,” Groundwater for Sustainable Development, 1, 50–58, 2015.

[2] R. Ahmad, R. Kumar, “Kinetic and thermodynamic studies of brilliant green adsorption onto arbon/Iron Oxide Nanocomposite,” Journal of the Korean Chemical Society, 54, 125-130, 2010.

[3] I. O. M. Copper, Dietary reference intakes for vitamin A vitamin K, arsenic, boron, chromium, copper, iodine, iron, manganese, molybdenum, nickel, silicon, vanadium, and zinc. Washington, DC: The National Academies Press, 2001.

[4] M. Malakootian, Z. Khashi, “Heavy metals contamination of drinking water supplies in southeastern villages of Rafsanjan plain: survey of arsenic, cadmium, lead and copper,” Journal of Health Field, 2, 1–9, 2014.

[5] E. I. Unuabonah, K.O. Adebowale, B.I. OluOwolabi, L.Z. Yang, “Comparison of sorption of PbP2+P and CdP2+P on Kaolinite clay and polyvinyl alcohol-modified Kaolinite clay,” Adsorption, 14, 791–803, 2008.

[6] A. Z. M. Badruddoza, Z. B. Z. Shawon, T. W. J. Daniel, K. Hidajat, M. S. Uddin, “Fe3O4/cyclodextrin polymer nanocomposites for selective heavy metals removal from industrial wastewater,” Carbohydrate Polymers, 91, 322–332, 2013.

[7] A. G. Fane, R. Wang, M. X. Hu, “Synthetic Membranes for Water Purification: Status and Future,” Angewandte Chemie International Edition, 54, 3368–3386, 2015.

[8] K. Yua, J. Ho, E. McCandlish, B. Buckleyb, R. Patelc, Z. Li, N. C. Shapley, “Copper ion adsorption by chitosan nanoparticles and alginate microparticles for water purification applications,”Colloids and Surfaces A, 425, 31–41, 2013.

[9] M. A. Al-Anber, “Removal of high-level Fe3+ from aqueous solution using natural inorganic materials: Bentonite (NB) and quartz (NQ),” Desalination, 250, 885–891, 2010.

[10] A. Baghel, B. Singh, P. Pandey, R.K. Dhaked, A.K. Gupta, K. Ganeshan, K. Sekhar, “Adsorptive removal of water poisons from contaminated water by adsorbents,” Journal of Hazardous Materials B,
137, 396–400, 2006.

[11] K. G. Bhattacharyya, S. S. Gupta, “Adsorptive accumulation of Cd(II), Co(II), Cu(II), Pb(II), and
Ni(II) from water on montmorillonite: Influence of acid activation,” Journal of Colloid Interface
Science, 310, 411–424, 2007.
[12] E. K. Putra, R. Pranowo, J. Sunarso, N. Indraswati, S. Ismadji, “Performance of activated carbon and bentonite for adsorption of amoxicillin from wastewater: Mechanisms, isotherms and kinetics,” water Research, 43, 2419–2430, 2009.

[13] H. Zheng, Y. Wang, Y. Zheng, H. Zhang, S. Liang, M. Long, “Equilibrium, kinetic and thermodynamic studies on the sorption of 4- hydroxyphenol on Cr-bentonite,” Chemical Engineering Journal, 143, 117–123, 2008.

[14] L. Zhi-rong, Z. Shao-qi, “Adsorption of copper and nickel on Na-bentonite,” Process Safety and Environmental Protection, 88, 62–66, 2010.

[15] L. Gu, J. Xu, L. Lv, B. Liu, H. Zhang, X. Yu, Z. Luo, “Dissolved organic nitrogen (DON) adsorption by using Al-pillared bentonite,” Desalination, 269, 206–213, 2011.

[16] J. Feng, X. Hu, P. L. Yue, “Novel Bentonite Clay-Based Fe-Nanocomposite as a Heterogeneous Catalyst for Photo-Fenton Discoloration and Mineralization of Orange II,” Environmental Science & Technology, 38, 269-275, 2004.

[17] H. Rezala, H. Khalaf, J. L. Valverde, A. Romero, A. Molinari, A. Maldotti, “Photocatalysis with Ti-pillared clays for the oxofunctionalization of alkylaromatics by O2,” Applied Catalysis A: General, 352, 234–242, 2009.

[18] X. Xiaofeng, G. Lian “Effect of crystal structure on adsorption behaviors of nanosized TiO2 for heavy-metal cations,” Current Applied Physics, 9, 185–188, 2009.

[19] J. Li, C. Chen, J. Zhao, H. Zhu, J. Orthman, “Photodegradation of dye pollutants on TiO2 nanoparticles dispersed in silicate under UV–VIS irradiation,” Applied Catalysis B: Environmental, 37, 331–338, 2002.

[20] M. Ishaq, S. Sultan, I. Ahmad, H. Ullah, M. Yaseen, A. Amir, “Adsorptive desulfurization of model oil using untreated, acid activated and magnetite nanoparticle loaded bentonite as adsorbent,” Journal of  audi Chemical Society, 21, 143–151, 2017.
[21] L. Z. Zhu, X.G. Ren, S.B. Yu, “Use of cetyltrimethylammonium bromide-bentonite to remove organic contaminants of varying polar character from water,” Environmental Science & Technology, 32, 3374–3378, 1998.

[22] H. Gupta, P. R. Gogate, “Intensified removal of copper from waste water using activated watermelon based biosorbent in the presence of ultrasound,” Ultrasonics Sonochemistry, 30, 113– 122, 2016.

[23] M. A. Hossain, H.H. Ngo, W.S. Guo, T.V. Nguyen, “Removal of copper form water by adsorption onto banana peel as biosorbent,” International Journal of Geomate, 2, 227–234, 2012.

[24] V. Masindi, W. M. Gitari, “Simultaneous removal of metal species from acidic aqueous solutions using cryptocrystalline magnesite/bentonite clay composite: an experimental and modelling approach,” Journal of Cleaner Production, 112, 1077-1085, 2016.

[25] Lalhmunsiama, S. M. Lee, D. Tiwari, “Manganese oxide immobilized activated carbons in the remediation of aqueous wastes contaminated with copper (II) and lead (II),” Chemical Engineering Journal, 225, 128–137, 2013.

[26] M. Vhahangwele, G. W. Mugera, “The potential of ball-milled South African bentonite clay for attenuation of heavy metals from acidic wastewaters: Simultaneous sorption of Co2+, Cu2+, Ni2+, Pb2+, and Zn2+ ions,” Journal of Environmental Chemical Engineering, 3, 2416–2425, 2015.

[27] D. Tiwari, Lalhmunsiama, S. M. Lee, “Ironimpregnated activated carbons precursor to rice hulls and areca nut waste in the remediation of Cu(II) and Pb(II) contaminated waters: a physico chemical studies,” Desalination and Water Treatment, 53, 1591–1605, 2015.
دوره 5، شماره 1
بهار 1397
صفحه 1-12

  • تاریخ دریافت 07 آبان 1399