Synthesis, Growth and Optical Properties Investigation of Cu-doped ZnSe Nanoparticles by Photochemical Method

Authors

Department of Physics, Faculty of Science, Vali-e-Asr University, Rafsanjan, Iran

Abstract

 
In the present work, Cu-doped ZnSe Nanocrystals NCs were synthesized by a simple photochemical method. XRD and TEM analysis demonstrated zinc blende phase NCs with an average size of around 3 nm. UV-Vis analysis showed decreasing the band gap of ZnSe NCs from 3.80 to 3.45 eV for 5 to 15 min illumination time. Photoluminescence spectra of ZnSe NCs showed a broad emission with two peaks located at 380 and 490 nm related to excitonic and trap states emission, respectively. For ZnSe:Cu NCs, excitonic emission was decreased and PL intensity of trap states emission increased and for 10 min illumination, excitonic emission quenched completely and trap states emission reached to its maximum value.

Keywords