Investigation of the effect of gamma irradiation on structural and optical properties of CdTe/CdSe quantum dots

Document Type : Original Article

Authors

1 department of physics vali-e-asr university rafsanjan iran

2 department of physics vali-e-asr university rafsanjan

3 هیئت علمی

4 department of physics vali-e-asr university Rafsanjan Iran

Abstract

Abstract: In this paper, effect of gamma irradiation on structural and optical properties of CdTe/CdSe QDs were investigated for the first time. X-ray diffraction (XRD) results showed that synthesized QDs had cubic structure and gamma irradiation had no change in crystalline structure of CdTe/CdSe QDs. Also, Fourier-transform infrared spectroscopy (FT-IR) results confirmed that crystalline structure of CdTe/CdSe QDs had no change after gamma irradiation. The photoluminescence (PL) results showed that intensity of CdTe/CdSe QDs after gamma irradiation enhanced significantly. Shell thickness of CdSe and concentration of QDs were investigated as two important factor on optical properties of CdTe/CdSe QDs versus gamma irradiation. The results showed that less shell thickness and less concentration of sample make bigger changes in optical properties and band gap size of CdTe/CdSe QDs after gamma irradiation and with decreasing concentration of the QDs, the red-shift in PL peak was occurred stronger. Our obtained results showed that luminescence and absorption of CdTe/CdSe QDs have sensitivity versus gamma irradiation and CdTe/CdSe QDs are good candidate to use in dosimetry applications.

Keywords


[1] M. Molaei, M. Marandi, E. Saievar-Iranizad, N. Taghavinia, B. Liu, H. D. Sun, and X. W. Sun, "Near-white emitting QD-LED based on hydrophilic CdS nanocrystals." Journal of Luminescence, 132, 467-473, 2012.
 
[2] N. Zeiri, A. Naifar, S. Abdi-Ben Nasrallah, and M. Said, "Theoretical studies on third nonlinear optical susceptibility in CdTe–CdS–ZnS core–shell–shell quantum dots." Photonics and Nanostructures-Fundamentals and Applications, 36, 100725, 2019.
 
 [3] D. Oluwole, J. Britton, P. Mashazi, and T. Nyokong. "Synthesis and photophysical properties of nanocomposites of aluminum tetrasulfonated phthalocyanine covalently linked to glutathione capped CdTe/CdS/ZnS quantum dots." Synthetic Metals, 205, 212-221, 2015.
 
[4] E. Zillner, J. Kavalakkatt, B. Eckhardt, T. Dittrich, A. Ennaoui, and M. Lux-Steiner. "Formation of a heterojunction by electrophoretic deposition of CdTe/CdSe nanoparticles from an exhaustible source." Thin Solid Films, 520, 17, 5500-5503, 2012.
 
[5] Z. Qiu, J. Shu, Y. He, Z. Lin, K.  Zhang, S. Lv, and D. Tang. "CdTe/CdSe quantum dot-based fluorescent aptasensor with hemin/G-quadruplex DNzyme for sensitive detection of lysozyme using rolling circle amplification and strand hybridization." Biosensors and Bioelectronics, 87, 18-24, 2017.
 
[6] M. M. Rahman, M. R. Karim, H. F. Alharbi, B. Aldokhayel, T. Uzzaman, and H. Zahir. "Cadmium Selenide quantum dots for solar cell applications: a review." Chemistry–An Asian Journal, 16, 8, 902-921, 2021.
 
  [7] V. Ncapayi, S. Parani, S. P. Songca, T.Kodama, and O.S. Oluwafemi. "Green synthesis of MPA-capped CdTe/CdSe quantum dots at different pH and its effect on the cell viability of fibroblast histiocytoma cells." Materials Letters, 209, 299-302, 2017.
 
 [8] A. Moulick, I. Blazkova, V. Milosavljevic, Z. Fohlerova, J. Hubalek, P. Kopel, M. Vaculovicova, V. Adam, and R. Kizek. "Application of CdTe/ZnSe quantum dots in in vitro imaging of chicken tissue and embryo." Photochemistry and photobiology, 91, 417-423, 2015.
 
 [9] A. Moulick, V. Milosavljevic, J. Vlachova, R. Podgajny, D. Hynek, P. Kopel, and V. Adam. "Using CdTe/ZnSe core/shell quantum dots to detect DNA and damage to DNA." International Journal of Nanomedicine, 12, 1277, 2017.
 
[10] T. Fu, H.Qin, H.Hu, Z. Hong, and S. He. "Aqueous synthesis and fluorescence-imaging application of CdTe/ZnSe core/shell quantum dots with high stability and low cytotoxicity." Journal of nanoscience and nanotechnology, 10, 1741-1746, 2010.
 
[11] Y. Li, W. Wang, D. Zhao, P. Chen, H. Du, Y. Wen, and X. Zhang. "Water-soluble fluorescent CdTe/ZnSe Core/Shell Quantum Dot: aqueous phase synthesis and cytotoxicity assays." Journal of nanoscience and nanotechnology, 15, 4648-4652, 2015.
 
 [12] F. Farahmandzadeh, M. Molaei, M. Karimipour, and A. R. Shamsi. "Highly luminescence CdTe/ZnSe core–shell QDs; synthesis by a simple low temperature approach." Journal of Materials Science: Materials in Electronics, 31, 15, 12382-12388, 2020.
 
 [13] L. Sai, and X. Y. Kong. "Microwave-assisted synthesis of water-dispersed CdTe/CdSe core/shell type II quantum dots." Nanoscale research letters, 6, 1-7, 2011.
[14] F. Wei X. Lu, Y. Wu, Z. Cai, L. Liu, P. Zhou, and Q. Hu. "Synthesis of highly luminescent CdTe/CdS/ZnS quantum dots by a one-pot capping method." Chemical engineering journal, 226, 416-422, 2013.
 
[15] H. Alehdaghi, E. Assar, B. Azadegan, J. Baedi, and A. A. Mowlavi. "Investigation of optical and structural properties of aqueous CdS quantum dots under gamma irradiation." Radiation Physics and Chemistry, 166, 108476, 2020.
[16] S. Chang, X.Wu, J. Lan, Z. Li, X. Zhang, and H. Zhang. "γ-Radiation enhanced luminescence of thiol-capped quantum dots in aqueous solution." Nanomaterials, 9, 4,506, 2019.
 
[17] N. Withers, K. Sankar, B. A. Akins, T. A. Memon, T. Gu, J. Gu, G. A. Smolyakov, M. R. Greenberg, T. J. Boyle, and M. Osiński. "Rapid degradation of Cd Se∕ Zn S colloidal quantum dots exposed to gamma irradiation." Applied Physics Letters 93, 17, 173101, 2008.  
 
[18] M. Molaei, H. Hasheminejad, and M. Karimipour. "Synthesizing and investigating photoluminescence properties of CdTe and CdTe@ CdS core-shell quantum dots (QDs): a new and simple microwave activated approach for growth of CdS shell around CdTe core." Electronic Materials Letters, 11, 1, 7-12, 2015.
 
[19] M. Nozaei, M. Molaei, F. Farahmandzadeh and B. Ramazanloo, "Synthesis and improvement of the optical peroperties of CdTe/CdSe core-shell QDs by using microwave approach." Nanomeghyas, 7, 61-67, 2020.
 
 [20] A. V.  Elevathoor, A. R. Jose, M. Jacob, and K. G. Kumar. "Thioglycolic acid capped CdS quantum dots as a fluorescent probe for the nanomolar determination of dopamine." Analytical Methods, 7, 16, 6791-6798, 2015.
 
[21] R. Xie, L. Li, Y. Li, L. Liu, D. Xiao, and J. Zhu. "Fe: ZnSe semiconductor nanocrystals: Synthesis, surface capping, and optical properties." Journal of alloys and compounds 509, 7, 3314-3318, 2011.
 
[22] K. Saikia, P. Deb, and E. Kalita. "Facile synthesis of highly luminescent ZnSe (S) alloyed quantum dot for biomedical imaging." Current Applied Physics, 13, 925-930, 2013.