ساخت و مشخصه‌یابی نانوصفحات اکسید سرب به روش سونوشیمی: اثر ماده‌ی فعال‌کننده‌ی سطحی

نویسندگان

گروه فیزیک، دانشکده فیزیک، دانشگاه یزد، یزد

چکیده

در این مطالعه، نانوصفحه‌های اکسید سرب به روش سونوشیمی در محیط آبی با موفقیت ساخته شد. برای مشخصه‌یابی نمونه‌ها از دستگاه‌های میکروسکوپ الکترونی روبشی ، پراش اشعه ایکس ، طیف سنج رامان، طیف‌سنج پراش انرژی پرتوی ایکس ، طیف‌سنج تبدیل فوریه مادون قرمز و طیف‌سنج نوری فرابنفش-مرئی استفاده شد. اثر ماده‌های فعال کننده سطحی پلی‌وینیل پیرولیدون لیگاند غیریونی و ستیل تری متیل آمونیوم برمید لیگاند کاتیونی بر روی سطح و خواص فیزیکی اکسید سرب بررسی شد. نتایج تصاویر میکروسکوپ الکترونی روبشی نشان میدهد استفاده از سورفکتانت پلی وینیل پیرولیدون باعث ایجاد نانوصفحات منظم با قطر متوسط µm 2 شده است. در صورتیکه استفاده از سورفکتانت ستیل تری متیل آمونیوم برماید به عنوان عامل پوششی، باعث تشکیل نانوذرات و میکروذرات شده است.

کلیدواژه‌ها


عنوان مقاله [English]

Synthesis and Characterization of PbO Nano-Plates by Sonochemical Method: Effect of Surfactants

نویسندگان [English]

  • S. Yazdani Darki
  • M. Eslami Kalantari
  • H. Zare
چکیده [English]

In this paper, PbO nanoplates were successfully prepared by a sonochemical method under ambient atmosphere and characterized by scanning electron microscopy SEM, X-ray diffraction XRD, Raman and UV–Vis spectroscopy, energy-dispersive X-ray analysis EDX and fourier transformed infrared spectroscopy FTIR. We studied the effect of additions of polyvinyl pyrrolidone a non-ionic ligand and cetyltrimethyl ammonium bromide a cationic ligand as surfactants on the structural and physical properties of PbO samples. The results of the SEM images show that the use of polyvinyl pyrrolidone surfactant has resulted in regular nanoplates with a mean diameter of 2 μm, while that of cetyltrimethyl ammonium as the surfactant result in nanoparticles and microparticles.

کلیدواژه‌ها [English]

  • Nanoplate
  • PbO
  • sonochemical method
  • polyvinyl pyrrolidone
  • cetyltrimethyl ammonium bromide
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