تأثیر توان خروجی التراسونیک و غلظت مواد اولیه روی اندازه نانو ساختار پلیمر کوئوردیناسیون کبالت(II) با پل ترفتالات و بررسی سطح هیرشفیلد

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه شیمی- دانشکده علوم پایه- دانشگاه آزاد اسلامی واحد تبریز- تبریز ایران

2 گروه شیمی- دانشکده علوم پایه- دانشگاه آزاد اسلامی واحد تبریز- تبریز- ایران

چکیده

بسپارکوئوردیناسیونی جدید از کبالت (II) در مقیاس نانو، (1) n[ Co(H2O)2 BDC ] BDC) = 1و4 بنزن دی کربوکسیلات یا ترفتالات) با نسبت مولی (1:1)  به روش سونوشیمیایی در غلظت­های (5/0، 25/0، 125/0) مولار از مواد اولیه و توان­های خروجی پروب التراسونیک (60،30 ،90 وات) و حمام اولتراسونیک با توان خروجی 50 وات سنتز شد. نانو ساختار بسپارکوئوردیناسیونی بدست آمده با روش­های طیف سنجی FT-IR، پراش پرتو ایکس پودری XRD))، UV-Vis و میکروسکوپ الکترونی روبشی (SEM) مورد شناسایی و بررسی قرار گرفت. پایداری دمایی این ترکیب بوسیله آنالیز وزن سنجی حرارتی (TGA) و آنالیز حرارتی سوختن (DTA) مورد مطالعه قرار گرفت. تأثیر غلظتهای متفاوت مواد اولیه و قدرت تابش اولتراسونیک بر مورفولوژی و اندازه نانو ساختار ترکیب (1)، مورد مطالعه قرار گرفت. با کلسیناسیون مستقیم ترکیب فوق در دمای 550 درجه سانتی گراد نانو ذرات اکسید کبالت Co3O4 تهیه شدند. این نانو ذرات بوسیله طیف سنجی XRD، FT-IR و تصاویرSEM   شناسایی شدند. بررسی سطح هیرشفلد نشان می­دهد که برهم­کنش­های O…O(25.7 %)،  O···H (15.8 %)، برهم­کنش­های C····O (12.0 %) و Co····O (9.0 %) نقش اصلی را در پایداری ساختار کریستالی دارند.

کلیدواژه‌ها


عنوان مقاله [English]

Effect of ultrasonic output power and initial reagents concentration on size Co(II) coordination polymer nanostructures with terephthalate bridge and Hirshfeld surface analysis

نویسندگان [English]

  • Gholam Hossein Shahverdizadeh 1
  • Shirin Shakibirad 2
1 Department of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, Iran
2 Department of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, Iran
چکیده [English]

Nano-sized of a new polymeric coordination [Co(H2O)2BDC]n (1), (BDC is benzene 1,4-dicarboxylate or terephthalate) (1:1), was synthesized by sonochemical method. The compound (1) was accomplished in three different concentrations of initial reagents (0.5, 0.25, 0.125M) and three different output power of ultrasonic generator (30, 60, 90W and ultrasonic bath with an output power of 50W). Nano-sized of compound (1) was characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and elemental analyses. The thermal stability of nano particles is studied by thermal gravimetric (TGA) and differential thermal analyses (DTA). The influence of various concentrations of initial reagents and power of ultrasound irradiation, on the morphology and size of nano-structured of compound (1), was studied. The compound (1) is then heated to 550o C to obtain Co3O4 nano particles. The nanoparticles of cobalt oxide are characterized by XRD, FT-IR spectroscopy and SEM images. Hirshfeld surface analysis revealed that the interactions O…O (25.7%), O···H (15.8%), C···O interactions (12.0%) and Co···O (9.0%) play the major role in the stability of the crystal structure.

کلیدواژه‌ها [English]

  • Coordination polymers
  • Cobalt(II)
  • Sonochemical
  • Nano structure
  • Hirshfeld surface analysis
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